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New nickel-containing homogeneous hydrogenation catalysts: Structures of [Ni(o-MeO-dpppol)Cl2] and [Ni(dcpe)Cl2]

✍ Scribed by Ingrid M. Angulo; Elisabeth Bouwman; Remy van Gorkum; Sandra M. Lok; Martin Lutz; Anthony L. Spek


Book ID
104422445
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
196 KB
Volume
202
Category
Article
ISSN
1381-1169

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## Abstract NiCl~2~Β·6H~2~O and 2,2′‐bipyridine (bipy) (1:1) were allowed to react under ambient conditions in dimethyl sulfoxide in the presence of acetylacetone (Hacac). The resulting green solution was concentrated in vacuo, and a green solid was isolated by precipitation with cold acetone. X‐ray