New Monocyclopentadienyl Complexes of Titanium(IV) and Zirconium(IV) with Chelating Pyrimidinethiolate, Oxypyrimidine, and Oxypyridine Ligands. Molecular Structure of [Zr(η 5 -C 5 Me 5 )(η 2 -O,N-ON 2 C 6 H 7 ) 3 ] †
✍ Scribed by Antiñolo, A.; Carrillo-Hermosilla, F.; Corrochano, A. E.; Fandos, R.; Fernández-Baeza, J.; Rodríguez, A. M.; Ruiz, M. J.; Otero, A.
- Book ID
- 127221765
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 127 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0276-7333
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## Abstract New monocyclopentadienyl species of Ta^V^, [Cp\*TaL~3~(XR)] (L = Cl, Me, X = O, S) bearing 4,6‐dimethyl‐2‐pyrimidinethiolate (SR = SC~6~H~7~N~2~) or 3‐cyano‐4,6‐dimethyloxypyridine (OR = OC~8~H~7~N~2~) ligands were prepared, namely [Cp\*TaCl~3~(SC~6~H~7~N~2~)] (1), [Cp\*TaCl~3~(OC~8~H~7
led to the isolation of the complex [{η 5 :η 2 -C 5 Me 4 CH 2 CH 2 N(Me)CN(C 6 H 3 Me 2 )}-TiCl 2 ] (6) by insertion The new organometallic binuclear complexes [{Cp\* Ti(NEt 2 )} 2 (µ-NEt) 2 ] (1), [(Cp\*Ti) 2 (NMe 2 )(NHMe 2 )(µ-NMe)(µ-of one isocyanide molecule into the titanium-nitrogen bond in 5