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New Molecular Assemblies of Redox Isomers, [Cr III (X 4 SQ) 3- n (X 4 Cat) n ] - n (X = Cl and Br; n = 0, 1, and 2), with Metallocenium Cations, [M III Cp 2 ] + (M = Co and Fe): X-ray Crystal Structures and Physical Properties

✍ Scribed by Chang, Ho-Chol; Miyasaka, Hitoshi; Kitagawa, Susumu


Book ID
120549603
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
219 KB
Volume
40
Category
Article
ISSN
0020-1669

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Metallacrown ethers with trans-tetracarb
✍ Christina H Duffey; Charles H Lake; Gary M Gray 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 263 KB

Photolysis of the cis-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%}, (1, n= 3; 2, n= 4; 3, n= 5) metallacrown ethers in tetrahydrofuran under nitrogen gives moderate yields of the corresponding trans-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%} (4, n =3; 5, n= 4; 6, n= 5) metallac