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New Models for the Study of the Racemization Mechanism of Carbodiimides. Synthesis and Structure (X-ray Crystallography and 1 H NMR) of Cyclic Carbodiimides

✍ Scribed by Molina, Pedro; Alajarín, Mateo; Sánchez-Andrada, Pilar; Carrió, Juan Server; Martínez-Ripoll, Martín; Anderson, J. Edgar; Jimeno, María Luisa; Elguero, José


Book ID
121440372
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
412 KB
Volume
61
Category
Article
ISSN
0022-3263

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## Abstract 1‐Hydroxymethylindazole and 1‐hydroxymethylbenzotriazole have been studied in solution by ^1^H, ^13^C and ^15^N NMR spectroscopy and the X‐ray structure of the second compound determined. DFT and GIAO calculations have been used to discuss geometries, energies (comparatively with 2‐subs