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New mixed valence iron oxides (Pb, A)Sr4Fe2O9 − δ (A = Cd, Hg) with the 0201-1201 inter growth type structure

✍ Scribed by N. Nguyen; P. Daniel; D. Groult; B. Raveau; J.M. Greneche


Book ID
113300686
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
542 KB
Volume
45
Category
Article
ISSN
0254-0584

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Pb1-xSr4Fe2O9-δ: A Layered Iron Oxide In
✍ S. Lucas; D. Groult; N. Nguyen; C. Michel; M. Hervieu; B. Raveau 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 597 KB

A new layered iron oxide, \(\mathrm{Pb}_{1-x} \mathrm{Sr}_{4} \mathrm{Fe}_{2} \mathrm{O}_{9-\delta}\), has been isolated for \(0 \leq x \leq 0.2\). Its structural model, which corresponds to a regular intergrowth of single \(\left[\mathrm{SrFeO}_{3_{-\delta}}\right\}_{x}\) perovskite layers with sin