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New methods for the selective reduction of disubstituted malonates to the corresponding hydroxy-ester derivatives

✍ Scribed by Timothy A. Ayers

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 256 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01100-4

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✦ Synopsis

The reduction of alkylphenylmalonates and dialkylmalonates with LiAI(O-t-Bu)3H proceeds with selective reduction of one of the ester functionalities to provide the hydroxy-ester derivatives in good yields.

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