New methodologies in trace analysis of volatile organic compounds

✍ Scribed by Roeraade, J. ;Blomberg, S.

• Publisher: John Wiley and Sons
• Year: 1989
• Tongue: English
• Weight: 371 KB
• Volume: 12
• Category: Article
• ISSN: 0935-6304
• DOI: 10.1002/jhrc.1240120305

✦ Synopsis

Two methods for sampling and concentration of volatile organic compounds are reported. In the first method, traps coated with a very thick film (ca. 100 pn) of cross-linked silicone stationary phase are employed. Such thick films can be prepared with a modified dynamic coating procedure, which is briefly described. The low phase ratio traps can be utilized for enrichment of volatiles from gaseous as well as aqueous matrices.

The second technique is based on chromatographic evaporation of a solvent in a capillary tube,where the process is sustained bya repeated sample injection and a cyclic flow reversal. In this way, large solvent volumes can be handled by a small volume system. Under optimal conditions, when using a solvent barrier, quantitative recovery is possible even for compounds of comparatively high volatility. Another important application of the technique is extraction of trace components from gases such as headspace samples, polluted air, etc.