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New method for the synthesis of metal complexes based on PtIVand substituted nicotinamides and isonicotinamides and investigation of their antimetastatic activity

✍ Scribed by B. S. Fedorov; M. A. Fadeev; G. I. Kozub; A. N. Chekhlov; N. P. Konovalova; T. E. Sashenkova; E. N. Berseneva; O. V. Dobrokhotova; L. V. Tatyanenko


Book ID
113079137
Publisher
Springer
Year
2011
Tongue
English
Weight
238 KB
Volume
60
Category
Article
ISSN
1573-9171

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Carbonylation of Transition-Metal Carbyn
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**Surprising reactions of carbon monoxide with transition metal complexes** have been observed with compounds __(1)__ and __(2)__. The carbyne complex __(1)__ takes up CO at normal pressure and βˆ’30Β°C to form the metalated ketene __(2)__ which itself is deoxygenated by CO at +60Β°C and under 60atm pre