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New method for synthesis of bifunctional tertiary phosphine oxides

✍ Scribed by V. K. Khairullin; G. V. Dmitrieva; I. A. Aleksandrova; M. A. Vasyanina

Book ID
112439509
Publisher
Springer
Year
1973
Tongue
English
Weight
334 KB
Volume
22
Category
Article
ISSN
1573-9171

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Tertiary phosphine oxides have been prepared with high enantiomeric excesses via intermediate menthyl 2-phosphinylacetates. Optically active phosphine oxides l\_ are key intermediates in the synthesis of bidentate phosphine ligands 2\_ useful for catalytic asymmetric homogeneous hydrogenation. 1) T