New method for isoquinuclidine synthesis. Total synthesis of desethylibogamine
β Scribed by Nagata, Wataru.; Hirai, Shoichi.; Kawata, Kyozo.; Okumura, Tamotsu.
- Book ID
- 126277550
- Publisher
- American Chemical Society
- Year
- 1967
- Tongue
- English
- Weight
- 348 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0002-7863
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Β±)-4'-Iodoindoimycenate 6 was stereoselectively converted into the (Β±)-(2,3)-syn-2thioacetoxy ester 16 with retention of C2-stereochemistry in (Β±)-6. Palladium-catalysed cyclisation of indolyl iodide and the internal C2 thiol group of the substrate (Β±)-17 derived from (Β±)-16 gave the (Β±)-cis methyl