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New Metal Chelates with Sterically Hindered Azo Ligands: Synthesis and Physicochemical Properties

✍ Scribed by V. A. Kogan; S. N. Lyubchenko; I. N. Shcherbakov; A. M. Ionov; V. V. Tkachev; G. V. Shilov; S. M. Aldoshin


Book ID
106522120
Publisher
SP MAIK Nauka/Interperiodica
Year
2005
Tongue
English
Weight
154 KB
Volume
31
Category
Article
ISSN
1070-3284

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New tin(IV) complexes with sterically hi
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## Abstract The reduction of 4,6‐di‐tert‐butyl‐N‐(2, 6‐di‐iso‐propylphenyl)‐o‐iminobenzoquinone (imQ) by tin amalgam in hexane solution leads to new six‐coordinated o‐iminoquinonato tin(IV) complex (iSQ)~2~SnAP (**1**) (where iSQ and AP are o‐iminosemiquinolate and dianion o‐amidophenolate, respect