New mechanism for the vibrational mode-specific proton-transfer reaction NH3+ (ν) + NH3 → NH2 + NH4+
✍ Scribed by Akitomo Tachibana; Tetsuo Suzuki; Naoto Yoshida; Yasuhiro Teramoto; Tokio Yamabe
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 486 KB
- Volume
- 156
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The mechanisms of the reactions of diborane with ammonia have been investigated by ab initio molecular orbital methods. The activation barrier of the formation of aminoborane, H,&NHr, from the adduct, H,B : NHs, of borane and ammonia is high (over 40 kcal/mol), because it is a reaction essentially
Line positions and line intensities of the nu1, nu3, and 2nu4 bands of 14NH3 were analyzed using line positions from 0.0054 cm-1 apodized resolution FT spectra recorded at Orsay and using line intensities from 0.011 cm-1 unapodized resolution FT spectra recorded at Kitt Peak National Observatory. Ab