Block copolymers consisting of methyl vinyl ether (MeVE) units and octadecyl vinyl ether (ODVE) units were synthesized using the cationic living polymerization technique. The polymerization of MeVE was initiated with the trimethyl silyl iodide/l,l-diethoxyethane/ZnI, system at -40Β°C in toluene and t
New Materials from poly(vinyl ethers)
β Scribed by Wouter G.S. Reyntjens; Eric J. Goethals
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 255 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1042-7147
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β¦ Synopsis
This paper gives an overview of the synthesis and properties of various kinds of amphiphilic segmented copolymers in which at least one of the segments is a poly(alkyl vinyl ether).
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## Abstract The living cationic random copolymerization of MVE and CEVE to obtain functionalized thermoβresponsive PMVE as precursors for more complex PMVEβcontaining polymer structures is reported. The random copolymers P(MVEβ__co__βCEVE) were synthesized at 0βΒ°C in toluene using the DEE/TMSI/ZnI~