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New marine diterpenoids, including a unique hydroperoxide, from a caribbean gorgonian coral of the genus pseudopterogorgia

✍ Scribed by Carl A. Harvis; Mark T. Burch; William Fenical

Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
251 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis

Three new diterpenoids related to the aglycone components of the recently described pseudopterosins and seco-pseudopterosins have been isolated from an undescribed Pseudopterogorgia species from the Caribbean Sea. The new compounds, described on the basis of their NMR properties and chemical interconversions, appear to be related illustrating some interesting rearrangements of a tertiary hydroperoxide in this series.

πŸ“œ SIMILAR VOLUMES

Erythrodiene: A new spirobicyclic sesqui
Erythrodiene: A new spirobicyclic sesquiterpene of a rare skeletal class from the caribbean gorgonian coral Erythropodium caribaeorum
✍ Charles Pathirana; William Fenical; Ethan Corcoran; J. Clardy πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 French βš– 148 KB

Erythrodiene (l) , a new sesquiterpene hydrocarbon of a rare structural class, has been isolated from the encrusting Caribbean gorgonian coral E~thropodiurn caribaeorum. The structure of the new compound was assigned on the basis of spectral studies and through an X-ray analysis of a reduced oxonol