New Ligands for the Titanium (IV)-Induced Asymmetric Reduction of Ketones with Catecholborane
✍ Scribed by Fredrik Almqvist; Lillemor Torstensson; Anette Gudmundsson; Prof. Torbjörn Frejd
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 297 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
Reductions performed with Ti(IV) complexes of ligands based on bicyclo[2.2.2]octane diols 5 and 6 are effective catalysts in the reduction of prochiral ketones to optically active alcohols, with catecholborane as the reducing agent. Methyl ketones are favored and enantiomeric excesses (ee) of < or =
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