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New Ligands for the Living Isotactic Anionic Polymerization of Methyl Methacrylate in Toluene at 0 °C. 1. Ligation of Butyllithium by Lithium Silanolates

✍ Scribed by Zundel, Thomas; Teyssié, Philippe; Jérôme, Robert


Book ID
120033504
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
81 KB
Volume
31
Category
Article
ISSN
0024-9297

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New initiator system for the anionic pol
✍ Catherine Zune; Thomas Zundel; Philippe Dubois; Philippe Teyssié; Robert Jérôme 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB 👁 2 views

Copolymerization of binary mixtures of alkyl (meth)acrylates has been initiated in toluene by a mixed complex of lithium silanolate O(s-BuMe 2 SiOLi)O and s-BuLi (molar ratio Ͼ 21) formed in situ by reaction of s-BuLi with hexamethylcyclotrisiloxane (D 3 ). Fully acrylate and methacrylate copolymers