New layered caesium zinc hydrogen phosphate, CsZn2.5(HPO4)3· 2H2O; synthesis, crystal structure and thermal transformation
✍ Scribed by Jensen, Torben R.; Hazell, Rita G.
- Book ID
- 125841320
- Publisher
- The Royal Society of Chemistry
- Year
- 2000
- Tongue
- English
- Weight
- 499 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1472-7773
- DOI
- 10.1039/B000714P
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📜 SIMILAR VOLUMES
Using 1, 4, 8, 11-tetraazacyclotetradecane (cyclam) as a template, a new layered zinc phosphate Zn 4 (PO 4 ) 2 (HPO 4 ) 2 ' 0.5(C 10 H 28 N 4 ) ' 2H 2 O (de5ned as ZnPO-cyclam) with 12-ring cavities was synthesized under hydrothermal conditions in a molar ratio ZnO:P 2 O 5 :cyclam:H 2 O ؍ 1:2.2:0.
We report the low-temperature \(\left(\sim 0^{\circ} \mathrm{C}\right)\) synthesis and \(\mathrm{X}\)-ray single-crystal structure of \(\mathrm{Na}_{2} \mathrm{Zn}\left(\mathrm{HPO}_{4}\right) \cdot 4!\mathrm{I}_{2} \mathrm{O}\), a new layered material, whose structure is built up from sheets of ver
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