New isomeric N-substituted hydrazones of 2-, 3-and 4-pyridinecarboxaldehydes
✍ Scribed by Elżbieta Wyrzykiewicz; Dorota Prukała
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1998
- Tongue
- English
- Weight
- 344 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0022-152X
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✦ Synopsis
Abstract
Eighteen compounds unknown in the literature, N‐(E)‐stilbenyloxyalkylcarbonyl‐ and N‐(E)‐stilbenyloxyalkylcarbonylaminoalkylcarbonyl‐substituted hydrazones of 2‐, 3‐ and 4‐pyridinecarboxaldehydes have been prepared. The stereochemical behavior of these compounds in dimethyl‐d~6~ sulfoxide solution has been studied by ^1^H‐nmr technique. The E geometrical isomers and cisltrans amide conformers have been found for N‐substituted‐hydrazones 1–16.
📜 SIMILAR VOLUMES
## Abstract EI induced mass spectral fragmentations of twelve new hydrazones of 2‐(3‐ and 4‐)‐pyridinecarboxaldehydes and hydrazides of (__E__)‐stilbenyloxyacetic acid as well as __N__‐(__E__)‐stilbenyloxyalkylcarbonyl substituted amino acids were investigated. Fragmentations pathways are proposed
## Abstract Twelve compounds unknown in the literature __N__‐(__E__)‐2‐stilbenyloxymethylenecarbonyl substituted hydrazones of 2‐, 3‐ and 4‐pyridinecarboxaldehydes, as well as methyl‐3‐pyridylketone have been prepared. The stereochemical behavior of these compounds in dimethyl‐d~6~ sulfoxide soluti
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