✍ Scribed by Elżbieta Wyrzykiewicz; Anna Szponar
No coin nor oath required. For personal study only.
Ten new ortho, meta and para substituted derivatives of 2‐benzylthio‐6‐aminouracils have been prepared. Electron Impact (EI) induced mass spectral fragmentation of these compounds was investigated. Fragmentation pathways are proposed on the basis of accurate mass and metastable transition measurements. The correlation between the intensities of the M^+^‐ and the selected fragment ions of these compounds is discussed. The data obtained create the basis for dinstinguishing isomers. The ^1^H and ^13^C NMR spectra of these compounds were assigned unambiguously using a combination of heteronuclear (HETCOR) spectra the chemical shifts. The data derived from these spectra can be used to differentiate the isomers.
📜 SIMILAR VOLUMES
The kinetics of chlorination of a number of ortho-, meta-, and para-substituted phenols by N-chloro-3-methyl-2,6-diphenylpiperidin-4-one (NCP) in acid medium have been investigated. The reaction is of first order with respect to oxidant and the order with respect to the substrate varies depending o
The kinetics of oxidation of a number of ortho, meta, and para substituted S-phenylmercaptoacetic acids by N-Chloro-3-Metyl-2,6-Diphenylpiperidin-4-one (NCP) has been studied in buffered ethanol-water (75:25 v/v) of pH 5.46. The reaction is of first order each in [oxidant] and [substrate]. The rate