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New Insight in the Synthesis and Reactivity of Selenenic Acids

✍ Scribed by Daniel Labar; Alain Krief

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
155 KB
Volume
93
Category
Article
ISSN
0037-9646

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✦ Synopsis

o-nitrophenyl aelanic acid haa been obaerved during the reduction of the corresponding seleninic acid with hypophosphorous acid. An acid catalysis was found eaaential for the addition of at least o-nitrophenyl aelenic acid to o h f i n . .

Selenlc acids have been postulated as intermediates in valuable synthetic reactions including the synthesis of olefins form s e l e n ~x i d e s ~-~

(Scheme 1) and the ayntheais of 8-hydroxyaelenidea from 01efina'-'~ and aeleninic acids in the preaence of diphenyldiaelenide', (Scheme 2) or hypophosphoroua acid9 (Scheme 3).

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