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New homogeneous rhodium catalysts for the regioselective hydroboration of alkenes

✍ Scribed by Westcott, Stephen A.; Blom, Henk P.; Marder, Todd B.; Baker, R. Thomas


Book ID
127345434
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
935 KB
Volume
114
Category
Article
ISSN
0002-7863

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A new promising in situ generated hydroborating agent, isopinocampheylbromoborane (IpcBHBr), achieves the asymmetric hydroboration of representative prochiral alkenes in pentane at lower temperatures, even at -78 Β°C, than has been possible with isopinocampheylborane (IpcBH2) and isopinocampheylchlor