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New High Nuclearity Platinum−Ruthenium Carbonyl Cluster Complexes Containing a Phenylacetylene Ligand: Structures and Properties

✍ Scribed by Adams, Richard D.; Captain, Burjor; Zhu, Lei

Book ID: 120510069
Publisher: American Chemical Society
Year: 2005
Tongue: English
Weight: 201 KB
Volume: 24
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om050175n

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## Abstract A direct and high‐yield synthetic route for a novel dodecanuclear osmium‐rhodium mixed‐metal cluster is presented. The redox properties of the cluster were examined, and it was found that the anion behaves as an “electron reservoir”. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim,