New Hg(II)–N-heterocyclic carbene complexes of compartmental ligands with a suitable topology for a η1-arene–Hg(II) close interaction

Synthesis and Crystal Structure of [(1-(

Synthesis and Crystal Structure of [(1-(Phenyltriazenido)-2-(phenyltriazeno)benzene)(nitrato)mercury(II)], {Hg[PhN3C6H4N3(H)Ph](NO3)}, a Complex with Weak Metal-Arene π-Interactions

✍ Manfredo Hörner; Adailton João Bortoluzzi; Johannes Beck; Michael Serafin 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 102 KB 👁 2 views

The reaction of PhN 3 (H)C 6 H 4 N 3 (H)Ph with Hg(NO 3 ) 2 in THF in the presence of triethylamine yields {Hg[PhN 3 C 6 H 4 N 3 (H)Ph](NO 3 )} as a yellow powder that can be recrystallized from THF/acetone. The crystals belong to the monoclinic system, space group P2 1 with the cell dimensions a ϭ