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New functionalizations of oxanorbornenic systems via 1,3-dipolar : cycloadditions with c,n-diphenylnitrone

✍ Scribed by Odon Arjona; Roberto Fernandez De La Pkadilla; Rosa A. Perez; Joaquin Plumet

Book ID: 104203701
Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 416 KB
Volume: 44
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)86090-7

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✦ Synopsis

The regio-and stereoselectivity of the c cloadditioa between C.N-diphenylnitrone and 2-endo-acetoxy-7-oxabicyclo 2.2.l]hept-S-enee 2-exo-carbonitrile has been studied. Subsequent fragmentation of the isoxazolidine ring with mCPBA followed by acidic hydrolysis yields highly functionalized oxanorbornenic hydroxyketones.

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