𝔖 Bobbio Scriptorium
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New fluorine derivatives of methylcyclohexasilane

✍ Scribed by Edwin F. Hengge; Karl Hassler; Franz Schrank

Book ID
102235257
Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
422 KB
Volume
1
Category
Article
ISSN
1042-7163

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✦ Synopsis

1 ,l -Difluorodecamethyl-and 1 ,I ,4,4-tetrafluorooctamethylcyclohexasilane were synthesized by the reaction of LiF with the corresponding trifluoromethanesulfonic derivatives and were characterized by spectroscopic methods, mainly by modern N M R techniques. The stability of the fluorinated cyclosilanes decreases with an increase of fluorine substituents. This seems to be the reason for the instability of perfluorinated cyclosilanes.

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