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New finding of a stable low-temperature phase in ferrocene crystal

✍ Scribed by Kouji Ogasahara; Michio Sorai; Hiroshi Suga

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
326 KB
Volume
68
Category
Article
ISSN
0009-2614

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✦ Synopsis

A stable lowtemperature phase nearly found in ferrocene is transformed into the usual high-temperature phase at 242 K, the enthalpy and entropy of transition being (4.145 + 0.005) kJ mol-' and (17-13 = O-02) JK-' mol-'. The well-known phase transition at 163.9 K found by Edwards et aL has been concluded to be a transition between metastabIe phases

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