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New ferraboranes. Structural analogs of hexaborane(10) and ferrocene. A complex of cyclic B5H10-, a counterpart of C5H5-

✍ Scribed by Weiss, Richard; Grimes, Russell N.


Book ID
126824657
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
288 KB
Volume
99
Category
Article
ISSN
0002-7863

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Phosphadicarbaborane Analogues of Ferroc
✍ Bohumil Ε tΓ­br; Josef Holub; Mario Bakardjiev; Ivan PavlΓ­k; OlegΒ L. Tok; Bernd Wr πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 122 KB

## Abstract Thermal isomerisation of the ferraphosphadicarbaborane [1‐Cp‐__closo__‐1,2,4,5‐FePC~2~B~8~H~10~] (1a; Cp = Ξ·^5^‐C~5~H~5~^βˆ’^) at elevated temperatures (180βˆ’350 Β°C) leads to the formation of three new isomeric complexes. These were characterized by multinuclear (^1^H, ^11^B, ^31^P, and ^1