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New efficient synthesis of Taniaphos ligands: application in ruthenium- and rhodium-catalyzed enantioselective hydrogenations

✍ Scribed by Katja Tappe; Paul Knochel

Book ID
108283698
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
629 KB
Volume
15
Category
Article
ISSN
0957-4166

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## Abstract A new class of low‐cost and easy‐to‐prepare monodentate phosphoramidite ligands (CydamPhos) has been developed from readily accessible and cheap __trans__‐1,2‐diaminocyclohexane as starting material through a three‐step transformation. This type of ligands exhibited excellent enantiosel