PM3 study of the domino reaction of nitr
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Luis R. Domingo; M. Teresa Picher; Juan AndrΓ©s
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Article
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1999
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John Wiley and Sons
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English
β 222 KB
π 2 views
The molecular mechanism of the domino reaction of nitroalkenes with silyl enol ethers to give nitroso acetal adducts was characterized using computational procedures at the PM3 semiempirical level. The domino process comprises three consecutive steps: the first and rate-determining step is the nucle