New direct transformation reaction of SiF4 with methanol and aluminum with the aid of iodine to prepare tetramethoxysilane and aluminum fluoride

ChemInform Abstract: A New Synthetic Rou

ChemInform Abstract: A New Synthetic Route to Allylsilanes: The Reaction of Silyllithium Reagents with Aromatic Carbonyl Compounds and Aluminum Tris(2,6- diphenylphenoxide) (ATPH).

✍ S. SAITO; K. SHIMADA; H. YAMAMOTO; E. MARTINEZ DE MARIGORTA; I. FLEMING 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 2 views

Tris(2,6-diphenylphenoxide) (ATPH). -1,6-Addition of silyllithium reagents to aromatic carbonyl compound ATPH complex and following enolate capture with an appropriate electrophilic reagent leads to functionalized allylsilanes shown in the scheme. In the reaction of (I), aromatic silylated products