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New Developments with Chiral Electrophilic Selenium Reagents

✍ Scribed by Danielle M. Browne; Thomas Wirth

Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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New chiral diselenides were prepared in a few steps from readily available starting materials. The selenium electrophiles generated from these diselenides were used for the efficient stereoselective inter-and intramolecular functionalization of alkenes. The substitution pattern influences the stereo

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## Abstract Very simple, chiral, non‐racemic diselenides were prepared and their corresponding selenium electrophiles were used for the stereoselective functionalization of alkenes. The influence of different alkenes on the outcome of the selenenylation reaction was investigated.