New deoxygenation reactions of sulfoxides, selenoxides and primary nitroalkanes to sulfides, selenides and nitriles
β Scribed by J.N. Denis; A. Krief
- Book ID
- 104237889
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 269 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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## Abstract Catalyst leaching from Pd and Ni particles stabilized by organic sulfur and selenium ligands occurs in solution in the presence of phosphanes. This process has been monitored in real time by 1D and 2D NMR spectroscopy and the nature of the metal species established. This catalyst leachi
## Abstract **The cover picture shows** the impact of the phosphane ligand on solid metal nanoparticles, which initiates transformation of the metal species into a highβperformance catalyst. The evolution of the transitionβmetal complexes was monitored by NMR spectroscopy, and the active form of th