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New cyclohexane- and cyclohexene-1,3-diones from tetraacetylethylene

โœ Scribed by Celli, Angela M.; Lampariello, Lucia R.; Chimichi, Stefano; Nesi, Rodolfo; Scotton, Mirella


Book ID
111954435
Publisher
NRC Research Press
Year
1982
Tongue
French
Weight
366 KB
Volume
60
Category
Article
ISSN
0008-4042

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A new synthetic pathway to spiro[cyclohexane-1,3 0 -indoline]-2 0 ,4-diones was found starting from 3-chloromethylene-2-indolones 1 and Danishefsky's diene 2. Their synthesis consists of several steps involving the formation of the cycloadducts, the 6-chloro-4-trimethylsilyloxy-2-methoxyspiro[cycloh