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New Cu(III) Oxychlorides in the Ba–Cu–M–O–Cl (M=Li, Na) System

✍ Scribed by K.A Thomas; G Calestani; F.C Matacotta; G Bocelli; K.V Ramanujachary; M Greenblatt

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
220 KB
Volume
129
Category
Article
ISSN
0022-4596

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✦ Synopsis

New Cu(III) oxychlorides with the stoichiometry Ba 4 (Cu, M ) O 4 Cl 4 (M ‫؍‬ Li, Na) have been identified in the title system under ambient synthetic conditions and are found to possess the layered K 2 NiF 4 -type structure.

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✍ K. Ruck; D. Eckert; G. Krabbes; M. Wolf; K.-H. Müller 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 538 KB

The polythermal section at a constant composition of 20 mol% BaCl 2 of the quasi-ternary system BaCl 2 -BaO-CuO x was investigated at p(O 2 ) ‫؍‬ 0.21 bar by means of DTA/TG and soaking experiments. Our results show the nature of incongruent decomposition reactions of the quaternary phases Ba 3 Cu 2