New Compounds.Phenacyl, p-Phenyl- and p-Bromophenacyl, and p-Nitrobenzyl Esters of Certain α-Hydroxy Fatty Acids
✍ Scribed by Price, Donald; Griffith, Richard
- Book ID
- 120427371
- Publisher
- American Chemical Society
- Year
- 1941
- Tongue
- English
- Weight
- 211 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0002-7863
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Gas phase carboxylate anions have been efficiently generated from the p-nitrobenzyl esters of nine fatty acids ranging in size from C6 to CZ2. The process involves the dissociative resonance capture of 2.9 eV electrons by the derivatives. The procedure is specific and gives the carboxylate anions as
New o-, m-and p-nitrobenzyl esters of lasalocid (o-ELAS, m-ELAS and p-ELAS) have been synthesised and studied by X-ray, 1 H, 13 C NMR, FT-IR, UV-Vis, fluorescence as well as PM5 semiempirical methods. The crystal structure of o-ELAS is stabilized by three intramolecular hydrogen bonds in which the k
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