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New Compounds. 3-( o -Methylbenzyloxy)-1,2-propanediol and 2, 2-Dimethyl-4-( o -methylbenzyloxymethyl)-1,3-dioxolane

✍ Scribed by Sauvage, G L.; Boekelheide, V.


Book ID
126791588
Publisher
American Chemical Society
Year
1949
Tongue
English
Weight
274 KB
Volume
71
Category
Article
ISSN
0002-7863

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(2,2-Dimethyl-Ξ±,Ξ±,Ξ±β€²,Ξ±β€²-tetraphenyl-1,3-
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The title compound, [Al(C~2~H~5~)(C~31~H~28~O~4~)(C~4~H~8~O)], has a slightly distorted tetrahedral geometry around the Al^III^ metal centre. The bidentate TADDOLate ligand and the Al^III^ metal atom form a seven-membered ring, with an Oβ€”Alβ€”O angle of 111.19β€…(10)Β°, which is close to the ideal tetrah