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New Complexes of Niobium(V) and Tantalum(V) with Monoanionic NNO Heteroscorpionate Ligands

✍ Scribed by Antonio Otero; Juan Fernández-Baeza; Antonio Antiñolo; Juan Tejeda; Agustín Lara-Sánchez; Luis Sánchez-Barba; Ana M. Rodríguez

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
166 KB
Volume
2004
Category
Article
ISSN
1434-1948

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📜 SIMILAR VOLUMES

Adducts of Niobium (V) and Tantalum (V)
Adducts of Niobium (V) and Tantalum (V) Halides. XV. Ligand Exchange of the Adducts with Some Phosphoryl Compounds
✍ Christian M. P. Favez; André E. Merbach 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 German ⚖ 414 KB

The ligand exchange MX5 . L + \*L 8 MX, . \*L + L for the octahedral adducts MX, . L, in an inert solvent (CH2CI2 or CHCI,) with neutral ligands, proceeds via a dissociative D mechanism when M = Nb, X = C1 and L= phosphoryl compound. A dissociative interchange Id mechanism is suggested when M = N b