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New coating systems based on vinyl ether- and oxetane-modified hyperbranched polyesters

โœ Scribed by D. Schmaljohann; B. I. Voit; J. F. G. A. Jansen; P. Hendriks; J. A. Loontjens

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
139 KB
Volume
275
Category
Article
ISSN
1438-7492

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Living cationic polymerization of vinyl
Living cationic polymerization of vinyl ethers with carboxylic acid/tin tetrahalide initiating systems. I. New initiating systems based on acetic acid and selection of Lewis acid and basic additive leading to living polymers with low polydispersity
โœ Tamotsu Hashimoto; Toshiaki Iwata; Atsushi Minami; Toshiyuki Kodaira ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 297 KB ๐Ÿ‘ 2 views

Cationic polymerization of isobutyl vinyl ether (IBVE) with acetic acid (CH 3 COOH)/tin tetrahalide (SnX 4 : X ฯญ Cl, Br, I) initiating systems in toluene solvent at 0ยฐC was investigated, and the reaction conditions for living polymerization of IBVE with the new initiating systems were established. A