New Class of Oligonuclear Platinum−Thallium Compounds with a Direct Metal-Metal Bond. 5. Structure Determination of Heterodimetallic Cyano Complexes in Aqueous Solution by EXAFS and Vibrational Spectroscopy
✍ Scribed by Jalilehvand, Farideh; Maliarik, Mikhail; Sandström, Magnus; Mink, János; Persson, Ingmar; Persson, Per; Tóth, Imre; Glaser, Julius
- Book ID
- 126929256
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 164 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0020-1669
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A new series of four binuclear platinum-thallium cyano compounds containing a direct and unsupported by ligands met-alϪmetal bond has been prepared in aqueous solution. These compounds are represented by the formula [(NC) 5 PtϪTl(CN) nϪ1 ] (nϪ1)Ϫ (n = 1Ϫ4 for compounds I, II, III IV, respectively) a
New Class of Oligonuclear Platinum-Thallium Compounds with a Direct Metal-Metal Bond. Part 2. Structural Characterization of the Complexes. -A new series of four binuclear Pt-Tl cyano compounds containing a direct metal-metal bond is prepared in aqueous solution from Pt(CN) 2-4 and Tl(CN) 3-n n (n =
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