✦ LIBER ✦
New chiral recognition of chiral tin(II) enolates toward cyclic acyl iminium species. Asymmetric total synthesis of (−)-supinidine
✍ Scribed by Yoshimitsu Nagao; Dal Wei-Min; Ochiai Masahito
- Book ID
- 104217728
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 230 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Diastereoselective alkylation of chiral tin(II) enolates l_onto cyclic acyl iminium ionLproceeded in a different chiral recognition nicde from the case of&onto the cyclic acyl imines 5 This new diastereoselective alkylation was efficiently utilized for an asymmetric total synthesis of (-)-supinidine (g>,