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New chiral ligands for catalytic asymmetric transfer hydrogenation of ketones

โœ Scribed by Yutong Jiang; Qiongzhong Jiang; Guoxin Zhu; Xumu Zhang


Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
210 KB
Volume
38
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


New chiral ligands 3 and 5 have been synthesized. Their Ru(II) complexes are effective catalysts for transfer hydrogenation of both aryl alkyl and dialkyl ketones (with ee's up to 79.5%).


๐Ÿ“œ SIMILAR VOLUMES


Chiral 1,1โ€ฒ-Diphosphetanylferrocenes: Ne
โœ Ulrich Berens; Mark J. Burk; Arne Gerlach; William Hems ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 92 KB ๐Ÿ‘ 1 views

The attainment of both high catalytic efficiency and high enantioselectivity remains a formidable challenge in asymmetric catalysis. [1] Bidentate ligands composed of trans-2,5disubstituted phospholane groups have been shown to be useful in asymmetric catalytic hydrogenation reactions. Despite high