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New Chalcogenidoarsenates with Transition Metal Complex Cations: [M(en)3]2As2S5 (M: Mn, Ni) and [Mn(en)3]2As2Se5.

✍ Scribed by Ding-Xian Jia; Qian-Xin Zhao; Jie Dai; Yong Zhang; Qin-Yu Zhu


Publisher
John Wiley and Sons
Year
2006
Weight
14 KB
Volume
37
Category
Article
ISSN
0931-7597

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Transition-Metal Complexes [(PMe3)2Cl2M(
✍ Pattiyil Parameswaran; Gernot Frenking πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 613 KB

## Abstract Density functional calculations at the BP86/TZ2P level were carried out to understand the ligand properties of the 16‐valence‐electron(VE) Groupβ€…14 complexes [(PMe~3~)~2~Cl~2~M(E)] (1ME) and the 18‐VE Groupβ€…14 complexes [(PMe~3~)~2~(CO)~2~M(E)] (2ME; M=Fe, Ru, Os; E=C, Si, Ge, Sn) in co