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New Cesium Hydrogen Selenate Phosphates: Synthesis and Crystal Structures

✍ Scribed by S.I. Troyanov; I.V. Morozov; V.B. Rybakov; A. Stiewe; E. Kemnitz


Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
516 KB
Volume
141
Category
Article
ISSN
0022-4596

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✦ Synopsis


All three compounds have in common a coordination number of cesium of 10 or 10Ψ‰1, with Cs-O distances from 2.9 to 3.8 A s . P and Se atoms form the individual tetrahedra with different H-bonding connectivity in structures I-III. PO 4 -SeO 4 layers with attached SeO 4 groups are present in I. Structure II contains a three-dimensional hydrogen bonding network, whereas structure III is characterized by PO 4 -SeO 4 bands to which additional SeO 4 tetrahedra are attached.


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