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New cationic hydrido and hydrido-dinitrogen complexes of iron

✍ Scribed by P. Giannoccaro; M. Rossi; A. Sacco

Book ID
117085055
Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
207 KB
Volume
8
Category
Article
ISSN
0010-8545

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The five-coordinate compound [RuHCl(CO)(PiPr 2 Ph) 2 ] (1), [RuHCl 2 (CO)(PiPr 2 Ph) 2 ] -contains the chloro ligands in cis and the phosphanes in trans disposition. The Ru=CH 2 bond which was prepared from RuCl 3 β€’ 3 H 2 O and PiPr 2 Ph in methanol in the presence of NEt 3 , reacts with CO and wit