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New case of formation of pterin ring

โœ Scribed by S. I. Zav'yalov; L. F. Ovechkina


Book ID
112438048
Publisher
Springer
Year
1974
Tongue
English
Weight
40 KB
Volume
23
Category
Article
ISSN
1573-9171

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Acyl radical insertion for the direct fo
โœ Jeff M. Pruet; Jon D. Robertus; Eric V. Anslyn ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 135 KB

A variety of pterin molecules were synthesized via an under-utilized acyl radical insertion, using aldehydes and a-keto esters as the acyl source. These reactions gave complete regiospecificity for the 7-isomer, with reaction times ranging in minutes, often with instantaneous product precipitation.