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New Carbonyl Compounds in the High-Boiling Fraction of Lavender Oil. 1st Communication

✍ Scribed by Roman Kaiser; Dietmar Lamparsky


Publisher
John Wiley and Sons
Year
1983
Tongue
German
Weight
420 KB
Volume
66
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

A series of new carbonyl compounds with santalane (3–9) as well as cadinane skeleton (10–13) have been identified for the first time in lavender oil. Most of the structures established by spectra interpretation are corroborated by partial synthesis starting from well‐defined natural products.


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New Carbonyl Compounds in the High-Boili
✍ Roman Kaiser; Dietmar Lamparsky 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 348 KB

## Abstract In addition to the sesquiterpenoid compounds reported in [1] the in‐depth analysis of lavender oil also led to the identification of new constituents with caryophyllane (**1**–**6**), cedrane (**7** and **8**) and other skeletons (**9**–**21**). Spectroscopic properties as well as parti

New Carbonyl Compounds in the High-Boili
✍ Roman Kaiser; Dietmar Lamparsky 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 German ⚖ 882 KB

## Abstract The occurrence of a series of new constituents which can be considered as __Diels‐Alder__ adducts of methyl vinyl ketone and ocimene (→1–4), myrcene (→**9**, **10**) or β‐far‐nesene ( →**11**, **12**), respectively, was reported. Furthermore, the structures of four isomeric cyclohexene