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New Bis(oxazolinyl)phenyl−Ruthenium(II) Complexes and Their Catalytic Activity for Enantioselective Hydrogenation and Transfer Hydrogenation of Ketones

✍ Scribed by Ito, Jun-ichi; Ujiie, Satoshi; Nishiyama, Hisao

Book ID: 121078920
Publisher: American Chemical Society
Year: 2009
Tongue: English
Weight: 214 KB
Volume: 28
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om800953f

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## Abstract A new and safer methodology has been developed for the synthesis of bis(pyrazol‐1‐yl)methane ligands (NN). Several ligands containing different phenyl groups on the central carbon atom have been obtained. Ruthenium derivatives of the type [Ru(arene)Cl(NN)]BPh~4~ (arene = benzene, __p__‐