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New Bis(lithiomethyl)silanes: Building Blocks for Organosilanes

✍ Scribed by Strohmann, Carsten ;Lüdtke, Silke ;Wack, Eric


Publisher
Wiley (John Wiley & Sons)
Year
1996
Tongue
English
Weight
733 KB
Volume
129
Category
Article
ISSN
0009-2940

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Bis- and tris(diazomethyl)phosphanes - n
✍ Harald Keller; Manfred Regitz 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 234 KB

The bisand tris(diazomethyl)phosphanes 5 and12 , obtained by electrophilic diasoalkane substitution of 4 or PC13 with lithiated 3 , are starting materials for complicated, heteroatom-substituted compounds. Thus, [3+2]-cycloadditions with the phosphaalkyne 9 and subsequent [1,5]-Tms shifts give rise