New Bis-biphosphole−Transition-Metal Complexes: Spontaneous Isomerization of trans- m eso - into cis -(±)-[Ru(trifluoroacetate) 2 (1,1‘-diphenyl-3,3‘,4,4‘- tetramethyl-2,2‘-biphosphole) 2 ]

New Rhodium(I) and Iridium(I) Complexes

New Rhodium(I) and Iridium(I) Complexes of the Chiral 1,1′-Diphenyl-3,3′,4,4′-tetramethyl-2,2′-biphosphole Ligand − Synthesis and Applications to Catalytic Hydrogenation and Hydroformylation Reactions

✍ Olivier Tissot; Maryse Gouygou; Frédéric Dallemer; Jean-Claude Daran; Gilbert G. 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 280 KB 👁 1 views

From a Lamellar to Hexagonal Self-Assemb

From a Lamellar to Hexagonal Self-Assembly of Bis(4,4′-(m,m′-di(dodecyloxy)phenyl)-2,2′-difluoro-1,3,2-dioxaborin) Molecules: A trans-to-cis-Isomerization-Induced Structural Transition Studied with STM

✍ Dirk Rohde; Cun-Ji Yan; Hui-Juan Yan; Li-Jun Wan 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 787 KB

From a Lamellar to Hexagonal Self-Assemb

From a Lamellar to Hexagonal Self-Assembly of Bis(4,4′-(m,m′-di(dodecyloxy)phenyl)-2,2′-difluoro-1,3,2-dioxaborin) Molecules: A trans-to-cis-Isomerization-Induced Structural Transition Studied with STM

✍ Dirk Rohde; Cun-Ji Yan; Hui-Juan Yan; Li-Jun Wan 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 788 KB

Metal dependent control of cis-/trans-1,

Metal dependent control of cis-/trans-1,4 regioselectivity in 1,3-butadiene polymerization catalyzed by transition metal complexes supported by 2,6-bis[1-(iminophenyl)ethyl]pyridine

✍ Dirong Gong; Baolin Wang; Chenxi Bai; Jifu Bi; Feng Wang; Weimin Dong; Xuequan Z 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 228 KB

Fe(III), Cr(III), Fe(II), Co(II) and Ni(II) chloride complexes supported by 2,6-bis [1-(iminophenyl)ethyl]pyridine have been synthesized and characterized along with single crystal X-ray diffraction. These complexes, in combination with MAO, have been examined in butadiene polymerization. The cataly

Transition metal complexes with bidentat

Transition metal complexes with bidentate ligand 2, 11-Bis (diphenylphosphinomethyl)benzo[c]phenanthrene (1). X. Preparation and spectroscopic properties of cis-[PtCl2 (1)] trans- and cis-[PtH (PPh3) (1)] [BF4] and crystal and molecular structure of cis-[PtCl2 (1)] · CHCl3

✍ Gustav Bracher; David M. Grove; Luigi M. Venanzi; Fiorella Bachechi; Pasquale Mu 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 German ⚖ 709 KB

## Abstract It is shown that ligand **1**, designed to span __trans__‐positions, under appropriate conditions also gives __cis__‐mononuclear complexes of platinum (II). The structure of __cis__‐[PtCl~2~ **(1)**] **(2)** has been determined by single‐crystal X‐ray diffraction. The major distortion f

Transition Metal Complexes with Sulfur L

Transition Metal Complexes with Sulfur Ligands. 136. 1 Enforced Trans Coordination of Thiolate Donors in Electron Rich Iron, Ruthenium, and Nickel [M(L)(pyN 2 H 2 S 2 )] and [M(L)(pyS 4 )] Complexes (L = CO, PPh 3 , DMSO) (pyN 2 H 2 S 22- = 2,6-Bis(2-mercaptophenylamino)dimethylpyridine(2−); pyS 42- = 2,6-Bis(2-mercaptophenylthio)dimethylpyridine(2−))

✍ Sellmann, Dieter; Utz, Jürgen; Heinemann, Frank W. 📂 Article 📅 1999 🏛 American Chemical Society 🌐 English ⚖ 304 KB