✦ LIBER ✦

New Aspects of Hydrogallation Reactions with Alkynes: Simple Addition versus Formation of Cyclophanes

✍ Scribed by Uhl, Werner; Haddadpour, Sima; Matar, Madhat

Book ID: 126918371
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 89 KB
Volume: 25
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om050776e

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Reactions of New Osmium−Dihydride Comple

Reactions of New Osmium−Dihydride Complexes with Terminal Alkynes: Metallacyclopropene versus Metal−Carbyne. Influence of the Alkyne Substituent

✍ Buil, María L.; Eisenstein, Odile; Esteruelas, Miguel A.; García-Yebra, Cristina 📂 Article 📅 1999 🏛 American Chemical Society 🌐 English ⚖ 261 KB

Comparison of the relative rates of radi

Comparison of the relative rates of radical addition versus diradical intermediate formation in [2 + 2] cycloaddition reactions of similarly substituted alkenes and alkynes

✍ Pasto, Daniel J.; Kong, Wei 📂 Article 📅 1989 🏛 American Chemical Society 🌐 English ⚖ 265 KB

Computational investigations of carbonyl

Computational investigations of carbonyl reactions: Comparison between nucleophilic addition versus enolate formation in the reaction of acetaldehyde with hydroxide ion

✍ Julianto Pranata 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 447 KB 👁 1 views

Reaction pathways leading to nucleophilic addition and enolate formation were investigated for the reaction between acetaldehyde and hydroxide anion. Ab initio calculations predict small activation barriers for both reactions in the gas phase. Monte Carlo simulations were performed to assess the eff

Factors governing cyclopropane versus py

Factors governing cyclopropane versus pyrazoline formation in the reaction of diazomethane with s-trinitrobenzene: Nucleophilic aromatic addition VIII

✍ J. Louwrier-De Wal; Th. J. de Boer 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 107 KB

Efficient Addition Reaction of Dibutylph

Efficient Addition Reaction of Dibutylphosphane Oxide with Alkynes: New Mechanistic Proposal Involving a Duo of Palladium and Brønsted Acid

✍ Jun Kanada; Masato Tanaka 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 320 KB 👁 1 views

## Abstract The addition reaction of dibutylphosphane oxide [Bu~2~P(O)H] with alkynes proceeds efficiently in the presence of palladium‐chelating phosphane–Brønsted acid catalyst systems. Terminal alkynes afford branched‐structured products selectively. On the other hand, the same reaction using mo

Corrigendum: Efficient Addition Reaction

Corrigendum: Efficient Addition Reaction of Dibutylphosphane Oxide with Alkynes: New Mechanistic Proposal Involving a Duo of Palladium and Brønsted Acid

✍ Jun Kanada; Masato Tanaka 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 54 KB 👁 1 views